Tricyclohexyl[2-(2,3-dimethylanilino)benzoato-κO]tin(IV)
نویسندگان
چکیده
In the title compound, [Sn(C(6)H(11))(3)(C(15)H(14)NO(2))], the Sn(IV) atom adopts a distorted tetra-hedral SnOC(3) arrangement. The dihedral angle between the benzene rings in the mefanamic acid mol-ecule is 82.16 (17)° and intra-molecular N-H⋯O and C-H⋯O hydrogen bonds help to establish the conformation. Two of the cyclo-hexyl rings are disordered over two sets of sites with equal occupancies.
منابع مشابه
Tricyclohexyl(2,3-dibromo-3-phenylpropionato-κO)tin(IV)
Tricyclo-hexyl-tin cinnamate reacts with 4,4-dimethyl-amino-pyridine hydro-bromide perbromide to form the title compound, [Sn(C(6)H(11))(3)(C(9)H(7)Br(2)O(2))], which exists as a monomeric mol-ecule with the Sn atom in a distorted tetra-hedral C(3)O coordination geometry.
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متن کاملCrystal structure of the 1:1 adduct of 2,3-diphenyl-3,4,5,6-tetrahydro-2H-1,3-thiazin-4-one with triphenyltin chloride
The title adduct, chlorido-(2,3-diphenyl-3,4,5,6-tetra-hydro-2H-1,3-thia-zin-4-one-κO)tri-phenyl-tin, [Sn(C6H5)3Cl(C16H15NOS)], resulted from reaction of 2,3-diphenyl-3,4,5,6-tetra-hydro-2H-1,3-thia-zin-4-one with tri-phenyl-tin chloride. The thia-zine ring has an envelope conformation with the S atom forming the flap. The mol-ecule has five phenyl rings, two of them attached to the thia-zine r...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009